New Synthetic Approach to Molecular Rods Using Cyclophosphazene-Based Oligospiranes

New Synthetic Approach to Molecular Rods Using Cyclophosphazene-Based Oligospiranes

A synthetic approach was developed to prepare a new type of highly functionalized inorganic–organic heterocyclic molecular rod (3a and 3b) consisting of cyclophosphazene and carbocyclic units. Single-crystal X-ray diffraction analysis of 3a revealed that the molecular length was ca. 2.5 nm. The prod...

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Veröffentlicht in:Inorganic chemistry 2017-08, Vol.56 (16), p.9413-9416
Hauptverfasser: Beşli, Serap, Mutlu Balcı, Ceylan, Uslu, Aylin, Allen, Christopher W
Format: Artikel
Sprache:eng
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Zusammenfassung:A synthetic approach was developed to prepare a new type of highly functionalized inorganic–organic heterocyclic molecular rod (3a and 3b) consisting of cyclophosphazene and carbocyclic units. Single-crystal X-ray diffraction analysis of 3a revealed that the molecular length was ca. 2.5 nm. The products of this high-yield process have the potential for derivatization via known phosphazene reactions.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.7b01715