Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generat...

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Veröffentlicht in:Journal of organic chemistry 2017-11, Vol.82 (22), p.11872-11876
Hauptverfasser: Qurban, Jihan, Elsherbini, Mohamed, Wirth, Thomas
Format: Artikel
Sprache:eng
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Zusammenfassung:Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.7b01571