Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex

Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex

A clamshell-type terbium(iii)-phthalocyaninato quadruple-decker complex was synthesized. Magnetic measurements revealed that Tb-Tb interactions caused an increase in the magnetic relaxation time and enhanced the SMM properties.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (61), p.8561-8564
Hauptverfasser: Horii, Yoji, Katoh, Keiichi, Breedlove, Brian K, Yamashita, Masahiro
Format: Artikel
Sprache:eng
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Zusammenfassung:A clamshell-type terbium(iii)-phthalocyaninato quadruple-decker complex was synthesized. Magnetic measurements revealed that Tb-Tb interactions caused an increase in the magnetic relaxation time and enhanced the SMM properties.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc03553e