Phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides: expedient access to triarylmethanes

Phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides: expedient access to triarylmethanes

We developed a novel phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides (p-QMs). This reaction provided a promising method for the synthesis of triarylmethanes, which widely exist in natural products and in molecules which have been shown to have biological and pharm...

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Veröffentlicht in:Organic & biomolecular chemistry 2017-06, Vol.15 (23), p.4941-4945
Hauptverfasser: Zhou, Tao, Li, Shenhuan, Huang, Ben, Li, Cao, Zhao, Yang, Chen, Jieqiong, Chen, Aoling, Xiao, Yuanjin, Liu, Lu, Zhang, Junliang
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Sprache:eng
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Zusammenfassung:We developed a novel phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides (p-QMs). This reaction provided a promising method for the synthesis of triarylmethanes, which widely exist in natural products and in molecules which have been shown to have biological and pharmacological activity.
ISSN:1477-0520
1477-0539
DOI:10.1039/c7ob00911a