Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations
A protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed. The reaction yields solid ion pairs consisting of donor dications and SF5-anions which can be effectively used in...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2017-06, Vol.19 (11), p.2571-2575 |
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| container_end_page | 2575 |
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| container_issue | 11 |
| container_start_page | 2571 |
| container_title | Green chemistry : an international journal and green chemistry resource : GC |
| container_volume | 19 |
| creator | Rueping, Magnus Nikolaienko, Pavlo Lebedev, Yury Adams, Alina |
| description | A protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed. The reaction yields solid ion pairs consisting of donor dications and SF5-anions which can be effectively used in fluorination reactions. |
| doi_str_mv | 10.1039/c7gc00877e |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2017-06, Vol.19 (11), p.2571-2575 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1915326631 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ambient temperature Fluorination Formations Greenhouse gases Ion pairs Reduction (metal working) Sulfur hexafluoride |
| title | Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations |
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