Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations

Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations

A protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed. The reaction yields solid ion pairs consisting of donor dications and SF5-anions which can be effectively used in...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2017-06, Vol.19 (11), p.2571-2575
Hauptverfasser: Rueping, Magnus, Nikolaienko, Pavlo, Lebedev, Yury, Adams, Alina
Format: Artikel
Sprache:eng
Schlagworte:
Ambient temperature
Fluorination
Formations
Greenhouse gases
Ion pairs
Reduction (metal working)
Sulfur hexafluoride
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Zusammenfassung:A protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed. The reaction yields solid ion pairs consisting of donor dications and SF5-anions which can be effectively used in fluorination reactions.
ISSN:1463-9262
1463-9270
DOI:10.1039/c7gc00877e