A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {Sb Sc W }, {Sb Sc W }, and {Sb Sc W }. These compounds include the largest Sc-containing polyoxotungstates and contain the largest number of Sc ions of any polyoxotungstates reported...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-05, Vol.46 (21), p.6848-6852
Hauptverfasser: Cai, Zhen-Wen, Yang, Tao, Qi, Yan-Jie, Li, Xin-Xiong, Zheng, Shou-Tian
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Nanostructure
Polyoxometallates
Scandium
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Zusammenfassung:We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {Sb Sc W }, {Sb Sc W }, and {Sb Sc W }. These compounds include the largest Sc-containing polyoxotungstates and contain the largest number of Sc ions of any polyoxotungstates reported to date.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt00892a