Controlled formation of ordered coordination polymeric networks using silsesquioxane building blocks

Controlled formation of ordered coordination polymeric networks using silsesquioxane building blocks

In this report, we synthesized ordered coordination polymers using polyhedral oligomeric silsesquioxanes (POSS) as a building block. A POSS with eight carboxylic terminals was coordinated with copper ions at various temperatures, forming polymeric networks. This novel coordination polymer has a long...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (43), p.17082-17086
Hauptverfasser: Banerjee, Subhabrata, Kataoka, Sho, Takahashi, Toshikazu, Kamimura, Yoshihiro, Suzuki, Kunio, Sato, Kazuhiko, Endo, Akira
Format: Artikel
Sprache:eng
Schlagworte:
Coordination polymers
Copper
Formations
Forming
Networks
Polyhedral oligomeric silsesquioxane
Synthesis (chemistry)
Terminals
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Zusammenfassung:In this report, we synthesized ordered coordination polymers using polyhedral oligomeric silsesquioxanes (POSS) as a building block. A POSS with eight carboxylic terminals was coordinated with copper ions at various temperatures, forming polymeric networks. This novel coordination polymer has a long-range ordered structure.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt02868c