Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal-organic frameworks

Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal-organic frameworks

The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal-organic frameworks represent a unique opportunity due to their tunable pore size, however aromatic linkers present strong absorption and reduce the transparen...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-06, Vol.46 (23), p.7397-7402
Hauptverfasser: Llabres-Campaner, P J, Pitarch-Jarque, J, Ballesteros-Garrido, R, Abarca, B, Ballesteros, R, García-España, E
Format: Artikel
Sprache:eng
Schlagworte:
Absorption
Confined environments
Metal-organic frameworks
Pore size
Porosity
Porous materials
Solvents
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Zusammenfassung:The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal-organic frameworks represent a unique opportunity due to their tunable pore size, however aromatic linkers present strong absorption and reduce the transparency. Herein, we report the first example of a MOF with bicyclic organic dicarboxylic linkers and its use as a solid solvent.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt00855d