A nonlinear optical active polymer film based on Pd(ii) dithione/dithiolate second-order NLO chromophores

A nonlinear optical active polymer film based on Pd(ii) dithione/dithiolate second-order NLO chromophores

A film of [Pd(R pipdt)(dmit)] (1), where R pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016-11, Vol.45 (43), p.17431-17438
Hauptverfasser: Espa, D, Pilia, L, Marchiò, L, Artizzu, F, Di Carlo, G, Marinotto, D, Serpe, A, Tessore, F, Deplano, P
Format: Artikel
Sprache:eng
Schlagworte:
Chromophores
Nonlinearity
Polymeric films
Polymethyl methacrylates
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A film of [Pd(R pipdt)(dmit)] (1), where R pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione-dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt02911f