Kinetics of CO2 Hydrogenation to Hydrocarbons over Iron–Silica Catalysts

The conversion of CO2 to hydrocarbons is increasingly seen as a potential alternative source of fuel and chemicals, while at the same time contributing to addressing global warming effects. An understanding of kinetics and mass transfer limitations is vital to both optimise catalyst performance and...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemphyschem 2017-11, Vol.18 (22), p.3211-3218
Hauptverfasser: Owen, Rhodri E., Mattia, Davide, Plucinski, Pawel, Jones, Matthew D.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 3218
container_issue 22
container_start_page 3211
container_title Chemphyschem
container_volume 18
creator Owen, Rhodri E.
Mattia, Davide
Plucinski, Pawel
Jones, Matthew D.
description The conversion of CO2 to hydrocarbons is increasingly seen as a potential alternative source of fuel and chemicals, while at the same time contributing to addressing global warming effects. An understanding of kinetics and mass transfer limitations is vital to both optimise catalyst performance and to scale up the whole process. In this work we report on a systematic investigation of the influence of the different process parameters, including pore size, catalyst support particle diameter, reaction temperature, pressure and reactant flow rate on conversion and selectivity of iron nanoparticle ‐silica catalysts. The results provided on activation energy and mass transfer limitations represent the basis to fully design a reactor system for the effective catalytic conversion of CO2 to hydrocarbons. CO2 conversion to hydrocarbons is a viable route to producing fuel and chemicals, while at the same time contributing to addressing global warming. Here we show that iron nanoparticle–silica systems can be effective catalysts for this reaction.
doi_str_mv 10.1002/cphc.201700422
format Article
fullrecord <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_miscellaneous_1914582884</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1914582884</sourcerecordid><originalsourceid>FETCH-LOGICAL-g4092-d2fcb593aed1658dd4ef52142fc9604e93b7f4c724671bf9e555343b55e65ccf3</originalsourceid><addsrcrecordid>eNpdkL1OwzAURi0EEqWwMkdiYUnxbxKPKAJaqFQkYLYcxy6uUrvYKSgb78Ab8iSkStWB6X7309HV1QHgEsEJghDfqM27mmCIcggpxkdghCjhaZ5RdLzPFBN2Cs5iXEEIC5ijEXh8sk63VsXEm6Rc4GTa1cEvtZOt9S5p_VAoGSrveuhTh2QWvPv9_nmxjVUyKWUrmy628RycGNlEfbGfY_B2f_daTtP54mFW3s7TJYUcpzU2qmKcSF2jjBV1TbVhGNG-5hmkmpMqN1TlmGY5qgzXjDFCScWYzphShozB9XB3E_zHVsdWrG1Uummk034bBeKIsgIXBe3Rq3_oym-D67_rqYwhkg0UH6gv2-hObIJdy9AJBMXOq9h5FQevonyeloeN_AGnSW5U</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1965136884</pqid></control><display><type>article</type><title>Kinetics of CO2 Hydrogenation to Hydrocarbons over Iron–Silica Catalysts</title><source>Access via Wiley Online Library</source><creator>Owen, Rhodri E. ; Mattia, Davide ; Plucinski, Pawel ; Jones, Matthew D.</creator><creatorcontrib>Owen, Rhodri E. ; Mattia, Davide ; Plucinski, Pawel ; Jones, Matthew D.</creatorcontrib><description>The conversion of CO2 to hydrocarbons is increasingly seen as a potential alternative source of fuel and chemicals, while at the same time contributing to addressing global warming effects. An understanding of kinetics and mass transfer limitations is vital to both optimise catalyst performance and to scale up the whole process. In this work we report on a systematic investigation of the influence of the different process parameters, including pore size, catalyst support particle diameter, reaction temperature, pressure and reactant flow rate on conversion and selectivity of iron nanoparticle ‐silica catalysts. The results provided on activation energy and mass transfer limitations represent the basis to fully design a reactor system for the effective catalytic conversion of CO2 to hydrocarbons. CO2 conversion to hydrocarbons is a viable route to producing fuel and chemicals, while at the same time contributing to addressing global warming. Here we show that iron nanoparticle–silica systems can be effective catalysts for this reaction.</description><identifier>ISSN: 1439-4235</identifier><identifier>EISSN: 1439-7641</identifier><identifier>DOI: 10.1002/cphc.201700422</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Carbon dioxide ; catalysis ; Catalysts ; Catalytic converters ; CO2 utilization ; Conversion ; Fischer–Topsch process ; Flow velocity ; heterogeneous catalysis ; Hydrocarbons ; Iron ; Mass transfer ; Nuclear fuels ; Pore size ; Porosity ; Process parameters ; Reaction kinetics ; reverse water–gas shift reaction ; Selectivity ; Silicon dioxide</subject><ispartof>Chemphyschem, 2017-11, Vol.18 (22), p.3211-3218</ispartof><rights>2017 Wiley‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-7679-4105</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcphc.201700422$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcphc.201700422$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Owen, Rhodri E.</creatorcontrib><creatorcontrib>Mattia, Davide</creatorcontrib><creatorcontrib>Plucinski, Pawel</creatorcontrib><creatorcontrib>Jones, Matthew D.</creatorcontrib><title>Kinetics of CO2 Hydrogenation to Hydrocarbons over Iron–Silica Catalysts</title><title>Chemphyschem</title><description>The conversion of CO2 to hydrocarbons is increasingly seen as a potential alternative source of fuel and chemicals, while at the same time contributing to addressing global warming effects. An understanding of kinetics and mass transfer limitations is vital to both optimise catalyst performance and to scale up the whole process. In this work we report on a systematic investigation of the influence of the different process parameters, including pore size, catalyst support particle diameter, reaction temperature, pressure and reactant flow rate on conversion and selectivity of iron nanoparticle ‐silica catalysts. The results provided on activation energy and mass transfer limitations represent the basis to fully design a reactor system for the effective catalytic conversion of CO2 to hydrocarbons. CO2 conversion to hydrocarbons is a viable route to producing fuel and chemicals, while at the same time contributing to addressing global warming. Here we show that iron nanoparticle–silica systems can be effective catalysts for this reaction.</description><subject>Carbon dioxide</subject><subject>catalysis</subject><subject>Catalysts</subject><subject>Catalytic converters</subject><subject>CO2 utilization</subject><subject>Conversion</subject><subject>Fischer–Topsch process</subject><subject>Flow velocity</subject><subject>heterogeneous catalysis</subject><subject>Hydrocarbons</subject><subject>Iron</subject><subject>Mass transfer</subject><subject>Nuclear fuels</subject><subject>Pore size</subject><subject>Porosity</subject><subject>Process parameters</subject><subject>Reaction kinetics</subject><subject>reverse water–gas shift reaction</subject><subject>Selectivity</subject><subject>Silicon dioxide</subject><issn>1439-4235</issn><issn>1439-7641</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNpdkL1OwzAURi0EEqWwMkdiYUnxbxKPKAJaqFQkYLYcxy6uUrvYKSgb78Ab8iSkStWB6X7309HV1QHgEsEJghDfqM27mmCIcggpxkdghCjhaZ5RdLzPFBN2Cs5iXEEIC5ijEXh8sk63VsXEm6Rc4GTa1cEvtZOt9S5p_VAoGSrveuhTh2QWvPv9_nmxjVUyKWUrmy628RycGNlEfbGfY_B2f_daTtP54mFW3s7TJYUcpzU2qmKcSF2jjBV1TbVhGNG-5hmkmpMqN1TlmGY5qgzXjDFCScWYzphShozB9XB3E_zHVsdWrG1Uummk034bBeKIsgIXBe3Rq3_oym-D67_rqYwhkg0UH6gv2-hObIJdy9AJBMXOq9h5FQevonyeloeN_AGnSW5U</recordid><startdate>20171117</startdate><enddate>20171117</enddate><creator>Owen, Rhodri E.</creator><creator>Mattia, Davide</creator><creator>Plucinski, Pawel</creator><creator>Jones, Matthew D.</creator><general>Wiley Subscription Services, Inc</general><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7679-4105</orcidid></search><sort><creationdate>20171117</creationdate><title>Kinetics of CO2 Hydrogenation to Hydrocarbons over Iron–Silica Catalysts</title><author>Owen, Rhodri E. ; Mattia, Davide ; Plucinski, Pawel ; Jones, Matthew D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g4092-d2fcb593aed1658dd4ef52142fc9604e93b7f4c724671bf9e555343b55e65ccf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Carbon dioxide</topic><topic>catalysis</topic><topic>Catalysts</topic><topic>Catalytic converters</topic><topic>CO2 utilization</topic><topic>Conversion</topic><topic>Fischer–Topsch process</topic><topic>Flow velocity</topic><topic>heterogeneous catalysis</topic><topic>Hydrocarbons</topic><topic>Iron</topic><topic>Mass transfer</topic><topic>Nuclear fuels</topic><topic>Pore size</topic><topic>Porosity</topic><topic>Process parameters</topic><topic>Reaction kinetics</topic><topic>reverse water–gas shift reaction</topic><topic>Selectivity</topic><topic>Silicon dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Owen, Rhodri E.</creatorcontrib><creatorcontrib>Mattia, Davide</creatorcontrib><creatorcontrib>Plucinski, Pawel</creatorcontrib><creatorcontrib>Jones, Matthew D.</creatorcontrib><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemphyschem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Owen, Rhodri E.</au><au>Mattia, Davide</au><au>Plucinski, Pawel</au><au>Jones, Matthew D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of CO2 Hydrogenation to Hydrocarbons over Iron–Silica Catalysts</atitle><jtitle>Chemphyschem</jtitle><date>2017-11-17</date><risdate>2017</risdate><volume>18</volume><issue>22</issue><spage>3211</spage><epage>3218</epage><pages>3211-3218</pages><issn>1439-4235</issn><eissn>1439-7641</eissn><abstract>The conversion of CO2 to hydrocarbons is increasingly seen as a potential alternative source of fuel and chemicals, while at the same time contributing to addressing global warming effects. An understanding of kinetics and mass transfer limitations is vital to both optimise catalyst performance and to scale up the whole process. In this work we report on a systematic investigation of the influence of the different process parameters, including pore size, catalyst support particle diameter, reaction temperature, pressure and reactant flow rate on conversion and selectivity of iron nanoparticle ‐silica catalysts. The results provided on activation energy and mass transfer limitations represent the basis to fully design a reactor system for the effective catalytic conversion of CO2 to hydrocarbons. CO2 conversion to hydrocarbons is a viable route to producing fuel and chemicals, while at the same time contributing to addressing global warming. Here we show that iron nanoparticle–silica systems can be effective catalysts for this reaction.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cphc.201700422</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-7679-4105</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1439-4235
ispartof Chemphyschem, 2017-11, Vol.18 (22), p.3211-3218
issn 1439-4235
1439-7641
language eng
recordid cdi_proquest_miscellaneous_1914582884
source Access via Wiley Online Library
subjects Carbon dioxide
catalysis
Catalysts
Catalytic converters
CO2 utilization
Conversion
Fischer–Topsch process
Flow velocity
heterogeneous catalysis
Hydrocarbons
Iron
Mass transfer
Nuclear fuels
Pore size
Porosity
Process parameters
Reaction kinetics
reverse water–gas shift reaction
Selectivity
Silicon dioxide
title Kinetics of CO2 Hydrogenation to Hydrocarbons over Iron–Silica Catalysts
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T01%3A23%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Kinetics%20of%20CO2%20Hydrogenation%20to%20Hydrocarbons%20over%20Iron%E2%80%93Silica%20Catalysts&rft.jtitle=Chemphyschem&rft.au=Owen,%20Rhodri%20E.&rft.date=2017-11-17&rft.volume=18&rft.issue=22&rft.spage=3211&rft.epage=3218&rft.pages=3211-3218&rft.issn=1439-4235&rft.eissn=1439-7641&rft_id=info:doi/10.1002/cphc.201700422&rft_dat=%3Cproquest_wiley%3E1914582884%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1965136884&rft_id=info:pmid/&rfr_iscdi=true