Transition-Metal-Free Photoinduced Intramolecular Annulation of 2,3-Di(hetero)­arylchromen-4-one

An efficient transition-metal-free photoinduced intracyclization of 4H-chromen-4-ones in EtOH–H2O (7:1, v/v) at ambient temperature for the construction of complicated fused-ring heteroaromatics is established. The reaction proceeds smoothly without requiring any catalysts/additives.

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Veröffentlicht in:Organic letters 2017-07, Vol.19 (13), p.3552-3555
Hauptverfasser: Han, Jie, Wang, Tao, Liang, Yong, Li, Ying, Li, Chenchen, Wang, Rui, Feng, Siqi, Zhang, Zunting
Format: Artikel
Sprache:eng
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Zusammenfassung:An efficient transition-metal-free photoinduced intracyclization of 4H-chromen-4-ones in EtOH–H2O (7:1, v/v) at ambient temperature for the construction of complicated fused-ring heteroaromatics is established. The reaction proceeds smoothly without requiring any catalysts/additives.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.7b01531