Bu4NI-Catalyzed Oxygen-Centered Radical Addition between Acyl Peroxides and Isocyanides

A novel oxygen-centered radical addition between acyl peroxides and isocyanides has been developed. A diverse collection of valuable arylcarboxyamides were easily synthesized by this protocol. From the preliminary mechanistic study, the elimination of carbon dioxide affords the product via an intram...

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Veröffentlicht in:	Organic letters 2017-06, Vol.19 (12), p.3147-3150
Hauptverfasser:	Chen, Meng, Li, Yang, Tang, Hong, Ding, Hao, Wang, Kai, Yang, Lingen, Li, Cuiting, Gao, Meng, Lei, Aiwen
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A novel oxygen-centered radical addition between acyl peroxides and isocyanides has been developed. A diverse collection of valuable arylcarboxyamides were easily synthesized by this protocol. From the preliminary mechanistic study, the elimination of carbon dioxide affords the product via an intramolecular rearrangement.
ISSN:	1523-7060 1523-7052
DOI:	10.1021/acs.orglett.7b01272