Slow Magnetic Relaxation in a Lanthanide-[1]Metallocenophane Complex
The first example of a lanthanide metallocenophane complex has been isolated as [Li(THF)4][DyFc3Li2(THF)2] (1). The molecular structure of complex 1 differs dramatically from those of main group and transition metal ferrocenophane complexes and features a distorted trigonal prismatic geometry arou...
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| Veröffentlicht in: | Journal of the American Chemical Society 2017-06, Vol.139 (24), p.8058-8061 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The first example of a lanthanide metallocenophane complex has been isolated as [Li(THF)4][DyFc3Li2(THF)2] (1). The molecular structure of complex 1 differs dramatically from those of main group and transition metal ferrocenophane complexes and features a distorted trigonal prismatic geometry around the Dy(III) ion and close intramolecular Dy···Fe distances. Furthermore, complex 1 exhibits all characteristics of a soft single-molecule magnet. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/jacs.7b01499 |