Built-in TTF–TCNQ charge-transfer salts in π-stacked pillared layer frameworks

Built-in TTF–TCNQ charge-transfer salts in π-stacked pillared layer frameworks

A TTF-TCNQ charge-transfer salt was incorporated in a layer structure with paddlewheel-type carboxylate-bridged dirhodium(ii, ii) complexes ([Rh2]) to construct pi -stacked pillared layer frameworks of formula (TTF)n[{Rh}2(TCNQ)] (n = 1 or 2).

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Veröffentlicht in:CrystEngComm 2017, Vol.19 (17), p.2300-2304
Hauptverfasser: Sekine, Yoshihiro, Tonouchi, Masanori, Yokoyama, Taiga, Kosaka, Wataru, Miyasaka, Hitoshi
Format: Artikel
Sprache:eng
Schlagworte:
Construction
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Zusammenfassung:A TTF-TCNQ charge-transfer salt was incorporated in a layer structure with paddlewheel-type carboxylate-bridged dirhodium(ii, ii) complexes ([Rh2]) to construct pi -stacked pillared layer frameworks of formula (TTF)n[{Rh}2(TCNQ)] (n = 1 or 2).
ISSN:1466-8033
1466-8033
DOI:10.1039/C7CE00492C