A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U of up to 387 cm , which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-05, Vol.53 (39), p.5416-5419
Hauptverfasser: Kazin, Pavel E, Zykin, Mikhail A, Trusov, Lev A, Eliseev, Artem A, Magdysyuk, Oxana V, Dinnebier, Robert E, Kremer, Reinhard K, Felser, Claudia, Jansen, Martin
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container_end_page 5419
container_issue 39
container_start_page 5416
container_title Chemical communications (Cambridge, England)
container_volume 53
creator Kazin, Pavel E
Zykin, Mikhail A
Trusov, Lev A
Eliseev, Artem A
Magdysyuk, Oxana V
Dinnebier, Robert E
Kremer, Reinhard K
Felser, Claudia
Jansen, Martin
description An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U of up to 387 cm , which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).
doi_str_mv 10.1039/c7cc02453c
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Apatite
Barriers
Channels
Cobalt
Magnetization
Phosphates
title A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation
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