A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation
An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U of up to 387 cm , which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2017-05, Vol.53 (39), p.5416-5419 |
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container_title | Chemical communications (Cambridge, England) |
container_volume | 53 |
creator | Kazin, Pavel E Zykin, Mikhail A Trusov, Lev A Eliseev, Artem A Magdysyuk, Oxana V Dinnebier, Robert E Kremer, Reinhard K Felser, Claudia Jansen, Martin |
description | An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U
of up to 387 cm
, which is well above the values for all so far known d-metal based single-molecule magnets (SMMs). |
doi_str_mv | 10.1039/c7cc02453c |
format | Article |
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issn | 1359-7345 1364-548X |
language | eng |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Apatite Barriers Channels Cobalt Magnetization Phosphates |
title | A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation |
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