A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U of up to 387 cm , which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-05, Vol.53 (39), p.5416-5419
Hauptverfasser: Kazin, Pavel E, Zykin, Mikhail A, Trusov, Lev A, Eliseev, Artem A, Magdysyuk, Oxana V, Dinnebier, Robert E, Kremer, Reinhard K, Felser, Claudia, Jansen, Martin
Format: Artikel
Sprache:eng
Schlagworte:
Apatite
Barriers
Channels
Cobalt
Magnetization
Phosphates
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Zusammenfassung:An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U of up to 387 cm , which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02453c