Fast, solvent-free and highly enantioselective fluorination of β-keto esters catalyzed by chiral copper complexes in a ball mill
A fast and highly enantioselective fluorination of beta -keto esters catalyzed by diphenylamine linked bis(oxazoline)-Cu(OTf)2 complexes under solvent-free conditions has been developed using a planetary ball mill. High yields, high enantioselectivities and shorter reaction times were achieved with...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2017-04, Vol.19 (7), p.1674-1677 |
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| container_end_page | 1677 |
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| container_issue | 7 |
| container_start_page | 1674 |
| container_title | Green chemistry : an international journal and green chemistry resource : GC |
| container_volume | 19 |
| creator | Wang, Yifeng Wang, Haojiang Jiang, Yidong Zhang, Cheng Shao, Juanjuan Xu, Danqian |
| description | A fast and highly enantioselective fluorination of beta -keto esters catalyzed by diphenylamine linked bis(oxazoline)-Cu(OTf)2 complexes under solvent-free conditions has been developed using a planetary ball mill. High yields, high enantioselectivities and shorter reaction times were achieved with low catalyst loading. |
| doi_str_mv | 10.1039/c6gc03306g |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2017-04, Vol.19 (7), p.1674-1677 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1904214034 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ball milling Catalysts Coordination compounds Copper Esters Fluorination Reaction time |
| title | Fast, solvent-free and highly enantioselective fluorination of β-keto esters catalyzed by chiral copper complexes in a ball mill |
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