Non-covalent π-π stacking interactions turn off non-adiabatic effects in proton-coupled electron transfer reactions

Non-covalent π-π stacking interactions turn off non-adiabatic effects in proton-coupled electron transfer reactions

π-π stacking interactions do not necessarily change the mechanism involved in the H transfer reaction between phenol and phenoxyl radicals. We propose that, in such cases, the e is transferred between the π delocalized moieties, while the H is transferred between the donor and acceptor atoms.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Physical chemistry chemical physics : PCCP 2017-03, Vol.19 (10), p.6969-6972
Hauptverfasser: Muñoz-Rugeles, Leonardo, Galano, Annia, Raúl Alvarez-Idaboy, J
Format: Artikel
Sprache:eng
Schlagworte:
Atomic properties
Electron transfer
Phenol
Physical chemistry
Radicals
Stacking
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:π-π stacking interactions do not necessarily change the mechanism involved in the H transfer reaction between phenol and phenoxyl radicals. We propose that, in such cases, the e is transferred between the π delocalized moieties, while the H is transferred between the donor and acceptor atoms.
ISSN:1463-9076
1463-9084
DOI:10.1039/c6cp08610a