Ar-P bond construction by the Pd-catalyzed oxidative cross-coupling of arylsilanes with H-phosphonates via C-Si bond cleavage

Ar-P bond construction by the Pd-catalyzed oxidative cross-coupling of arylsilanes with H-phosphonates via C-Si bond cleavage

A novel and efficient methodology that allows for the construction of Ar-P bonds via the Pd-catalyzed oxidative cross-coupling reaction of various arylsilanes with H-phosphonates leading to valuable arylphosphonates has been developed.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (5), p.956-958
Hauptverfasser: Luo, Haiqing, Liu, Haidong, Chen, Xingwei, Wang, Keke, Luo, Xuzhong, Wang, Kejun
Format: Artikel
Sprache:eng
Schlagworte:
Chemical bonds
Chemical reactions
Cleavage
Cross coupling
Methodology
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Beschreibung
Zusammenfassung:A novel and efficient methodology that allows for the construction of Ar-P bonds via the Pd-catalyzed oxidative cross-coupling reaction of various arylsilanes with H-phosphonates leading to valuable arylphosphonates has been developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/C6CC08408G