In situ growth of Pt3Ni nanoparticles on an A-site deficient perovskite with enhanced activity for the oxygen reduction reaction

A novel A-site deficient perovskite, La0.9Mn0.9Pt0.075Ni0.025O3- delta , is developed as a catalyst for the oxygen reduction reaction in alkaline solution. Pt3Ni nanoparticles are exsolved in situ on the surface upon reduction. The catalytic activity improves significantly after exsolution. This imp...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2017-04, Vol.5 (14), p.6399-6404
Hauptverfasser: Gao, Yang, Wang, Jian, Lyu, Yu-Qi, Lam, Kwunyu, Ciucci, Francesco
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Sprache:eng
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Zusammenfassung:A novel A-site deficient perovskite, La0.9Mn0.9Pt0.075Ni0.025O3- delta , is developed as a catalyst for the oxygen reduction reaction in alkaline solution. Pt3Ni nanoparticles are exsolved in situ on the surface upon reduction. The catalytic activity improves significantly after exsolution. This improvement is attributed to the synergy between the host perovskite and the nanoparticles.
ISSN:2050-7488
2050-7496
DOI:10.1039/c7ta00349h