Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(ii) and Fe(ii) m-terphenyl complexes

Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(ii) and Fe(ii) m-terphenyl complexes

Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (5), p.937-940
Hauptverfasser: Sharpe, Helen R, Geer, Ana M, Williams, Huw E L, Blundell, Toby J, Lewis, William, Blake, Alexander J, Kays, Deborah L
Format: Artikel
Sprache:eng
Schlagworte:
Aliphatic compounds
Catalysis
Catalysts
Iron
Isocyanates
Manganese
Reaction time
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Beschreibung
Zusammenfassung:Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc07243g