Palladium-Catalyzed C(sp2)–H Acetoxylation via Electrochemical Oxidation

Palladium-Catalyzed C(sp2)–H Acetoxylation via Electrochemical Oxidation

Palladium-catalyzed arene C­(sp2)–H acetoxylation has emerged as a powerful tool to construct a carbon–oxygen (C–O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage. To solve this fundamental problem, we now report an ano...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2017-06, Vol.19 (11), p.2905-2908
Hauptverfasser: Li, Yi-Qian, Yang, Qi-Liang, Fang, Ping, Mei, Tian-Sheng, Zhang, Dayong
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Palladium-catalyzed arene C­(sp2)–H acetoxylation has emerged as a powerful tool to construct a carbon–oxygen (C–O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage. To solve this fundamental problem, we now report an anodic oxidation strategy to achieve arene C­(sp2)–H acetoxylation.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.7b01138