Copper-catalyzed hydroallylation of allenes employing hydrosilanes and allyl chlorides

Copper-catalyzed hydroallylation of allenes employing hydrosilanes and allyl chlorides

The hydroallylation of allenes was developed by employing a hydrosilane and allyl chlorides in the presence of a copper catalyst. The reaction provided (E)-1,5-dienes mainly in good to high yields.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (56), p.7898-7900
Hauptverfasser: Fujihara, Tetsuaki, Yokota, Ken, Terao, Jun, Tsuji, Yasushi
Format: Artikel
Sprache:eng
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Zusammenfassung:The hydroallylation of allenes was developed by employing a hydrosilane and allyl chlorides in the presence of a copper catalyst. The reaction provided (E)-1,5-dienes mainly in good to high yields.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02816d