Dynamic covalent assembly of tribenzotriquinacenes into molecular cubes

Dynamic covalent assembly of tribenzotriquinacenes into molecular cubes

Molecular cubes constructed from catechol-functionalized tribenzotriquinacenes and 1,4-phenylene diboronic acids were synthesized in a one-pot procedure by crosslinking 20 individual components through a dynamic covalent approach. Structural identity of the nanocubes was confirmed by mass spectromet...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (83), p.12454-12457
Hauptverfasser: Klotzbach, Stefanie, Scherpf, Thorsten, Beuerle, Florian
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Covalence
Crosslinking
Cubes
Dynamics
Mass spectrometry
Nanostructure
Spectroscopy
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Zusammenfassung:Molecular cubes constructed from catechol-functionalized tribenzotriquinacenes and 1,4-phenylene diboronic acids were synthesized in a one-pot procedure by crosslinking 20 individual components through a dynamic covalent approach. Structural identity of the nanocubes was confirmed by mass spectrometry and (1)H-NMR spectroscopy.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc01794c