Metal-free cascade construction of C-C bonds by activation of inert C(sp3)-H bonds

Metal-free cascade construction of C-C bonds by activation of inert C(sp3)-H bonds

A new synthetic strategy for C-C bond formation has been developed via a free radical cascade process under metal-free conditions. Activation of inert C(sp(3))-H/elimination of SO2/C-C bond formation were achieved in sequence in this system.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (7), p.1320-1322
Hauptverfasser: Zhang, Honglin, Pan, Changduo, Jin, Ning, Gu, Zhangxi, Hu, Hongwen, Zhu, Chengjian
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Bonding
Carbon-carbon composites
Cascades
Chemical bonds
Free radicals
Inert
Strategy
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Zusammenfassung:A new synthetic strategy for C-C bond formation has been developed via a free radical cascade process under metal-free conditions. Activation of inert C(sp(3))-H/elimination of SO2/C-C bond formation were achieved in sequence in this system.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc08629e