Photobiocatalytic decarboxylation for olefin synthesis

Photobiocatalytic decarboxylation for olefin synthesis

Here, we describe the combination of OleTJE with a light-driven in situ H2O2-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes. The photobiocatalytic system shows clear advantages regarding enzyme activity and yield, resulting in a simple and effici...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (10), p.1918-1921
Hauptverfasser: Zachos, Ioannis, Gassmeyer, Sarah Katharina, Bauer, Daniel, Sieber, Volker, Hollmann, Frank, Kourist, Robert
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Alkenes - chemical synthesis
Alkenes - chemistry
Carboxy-Lyases - genetics
Carboxy-Lyases - metabolism
Conversion
Decarboxylation
Enzyme activity
Escherichia coli - genetics
Fatty acids
Fatty Acids - chemistry
Hydrogen Peroxide - chemistry
Light
Olefins
Synthesis
Terminals
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Beschreibung
Zusammenfassung:Here, we describe the combination of OleTJE with a light-driven in situ H2O2-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes. The photobiocatalytic system shows clear advantages regarding enzyme activity and yield, resulting in a simple and efficient system for fatty acid decarboxylation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc07276f