Sulfonyl chlorides as an efficient tool for the postsynthetic modification of Cr-MIL-101-SO sub(3)H and CAU-1-NH sub(2)

Sulfonyl chlorides as an efficient tool for the postsynthetic modification of Cr-MIL-101-SO sub(3)H and CAU-1-NH sub(2)

Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO sub(3)H and CAU-1-NH sub(2) have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-07, Vol.50 (66), p.9306-9308
Hauptverfasser: Klinkebiel, Arne, Reimer, Nele, Lammert, Martin, Stock, Norbert, Luening, Ulrich
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Chlorides
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container_issue 66
container_start_page 9306
container_title Chemical communications (Cambridge, England)
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creator Klinkebiel, Arne
Reimer, Nele
Lammert, Martin
Stock, Norbert
Luening, Ulrich
description Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO sub(3)H and CAU-1-NH sub(2) have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound to the framework either by its N or its S atom.
doi_str_mv 10.1039/c4cc03746d
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chlorides
title Sulfonyl chlorides as an efficient tool for the postsynthetic modification of Cr-MIL-101-SO sub(3)H and CAU-1-NH sub(2)
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