Sulfonyl chlorides as an efficient tool for the postsynthetic modification of Cr-MIL-101-SO sub(3)H and CAU-1-NH sub(2)

Sulfonyl chlorides as an efficient tool for the postsynthetic modification of Cr-MIL-101-SO sub(3)H and CAU-1-NH sub(2)

Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO sub(3)H and CAU-1-NH sub(2) have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-07, Vol.50 (66), p.9306-9308
Hauptverfasser: Klinkebiel, Arne, Reimer, Nele, Lammert, Martin, Stock, Norbert, Luening, Ulrich
Format: Artikel
Sprache:eng
Schlagworte:
Chlorides
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Zusammenfassung:Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO sub(3)H and CAU-1-NH sub(2) have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound to the framework either by its N or its S atom.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03746d