Targeted synthesis of a large triazine-based [4+6] organic molecular cage: structure, porosity and gas separation

Herein, we report the targeted synthesis and solid state assembly of a novel triazine-based [4+6] organic molecular cage. The tetrahedral cage features a large cavity (∼2070 Å(3)), and after desolvation, the resultant material exhibits a high Brunauer-Emmett-Teller surface area of 1181 m(2) g(-1) an...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (10), p.1976-1979
Hauptverfasser:	Ding, Huimin, Yang, Yihui, Li, Bijian, Pan, Feng, Zhu, Guozhu, Zeller, Matthias, Yuan, Daqiang, Wang, Cheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Assembly Cage Carbon dioxide Chemistry Techniques, Analytical - instrumentation Gases - isolation & purification Holes Organic chemistry Porosity Surface area Synthesis (chemistry) Triazines - chemical synthesis Triazines - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Herein, we report the targeted synthesis and solid state assembly of a novel triazine-based [4+6] organic molecular cage. The tetrahedral cage features a large cavity (∼2070 Å(3)), and after desolvation, the resultant material exhibits a high Brunauer-Emmett-Teller surface area of 1181 m(2) g(-1) and also features selective adsorption of CO2 over N2.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c4cc08883b