Formation of carbon phases under hydrothermal conditions

The formation of carbon phases by reacting formaldehyde with sulfuric acid under hydrothermal conditions was studied. The final products of the reaction were found to be amorphous carbon, diamond-like carbon, α- and β-graphite phases, fullerenes C 60 and C 70 , fullerites, carbolite, and chaoite. Hy...

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Veröffentlicht in:	Russian journal of inorganic chemistry 2016-11, Vol.61 (11), p.1374-1377
Hauptverfasser:	Kozhbakhteev, E. M., Skorikov, V. M., Milenov, T. I., Kuznetsova, S. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Buckminsterfullerene Carbon Chemistry Chemistry and Materials Science Cyclic hydrocarbons Diamond-like carbon Formations Fullerenes Hydrocarbons Inorganic Chemistry Phases Reaction products Sulfuric acid Synthesis and Properties of Inorganic Compounds
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Zusammenfassung:	The formation of carbon phases by reacting formaldehyde with sulfuric acid under hydrothermal conditions was studied. The final products of the reaction were found to be amorphous carbon, diamond-like carbon, α- and β-graphite phases, fullerenes C 60 and C 70 , fullerites, carbolite, and chaoite. Hydrocarbons of various compositions were detected in reaction products, namely cyclic hydrocarbons, including aromatic ones, and naphthene hydrocarbons. A formation scheme is suggested for carbon structures.
ISSN:	0036-0236 1531-8613
DOI:	10.1134/S0036023616110103