C-HCl- hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

C-HCl- hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

Structural evidence is reported for C-HCl- hydrogen bonds in solution and in the solid state of HgCl2 complexes with cyclen-based cryptands. These cyclen-based cryptands (1) and (2) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicat...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-03, Vol.46 (12), p.3800-3804
Hauptverfasser: Ikeda, Mari, Sah, Ajay Kumar, Iwase, Miki, Murashige, Rina, Ishi-I, Jun-Ichi, Hasegawa, Masatoshi, Kachi-Terajima, Chihiro, Park, Ki-Min, Kuwahara, Shunsuke, Habata, Yoichi
Format: Artikel
Sprache:eng
Schlagworte:
Acetonitrile
Aromatic compounds
Holes
Hydrogen bonds
Molecular structure
Solid state
Triethylene glycol
X rays
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Zusammenfassung:Structural evidence is reported for C-HCl- hydrogen bonds in solution and in the solid state of HgCl2 complexes with cyclen-based cryptands. These cyclen-based cryptands (1) and (2) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicates that the 2/HgCl2 complex contains an acetonitrile molecule in the cavity.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt03390c