Extended supramolecular organization of π-systems using yet unexplored simultaneous intra- and inter-molecular H-bonding motifs of 1,3-dihydroxy derivatives

Extended supramolecular organization of π-systems using yet unexplored simultaneous intra- and inter-molecular H-bonding motifs of 1,3-dihydroxy derivatives

Unique H-bonding motifs of 1,3-dihydroxyl derivatives involving simultaneous intra- and inter-molecular H-bonding results in extended organization of pendant chromophores with a spatial distance suitable for π-π interaction. A preformed assembly with appended acceptor units exhibits host-guest inter...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (24), p.5040-5043
Hauptverfasser: Mondal, Tathagata, Basak, Dipankar, Al Ouahabi, Abdelaziz, Schmutz, Marc, Mésini, Philippe, Ghosh, Suhrit
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Chromophores
Complex formation
Derivatives
Organizations
Supramolecular compounds
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Zusammenfassung:Unique H-bonding motifs of 1,3-dihydroxyl derivatives involving simultaneous intra- and inter-molecular H-bonding results in extended organization of pendant chromophores with a spatial distance suitable for π-π interaction. A preformed assembly with appended acceptor units exhibits host-guest interaction with specific donors by charge-transfer complex formation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc10335a