Synthesis of a mixed valence state Ce-MOF as an oxidase mimetic for the colorimetric detection of biothiols

We demonstrate a facile and rapid in situ partial oxidation synthetic strategy for the fabrication of a mixed valence state Ce-MOF (MVCM) which exhibits intrinsic oxidase-like activity. Furthermore, on the basis of the excellent catalytic activity of the MCVM, a colorimetric approach for the high-th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (22), p.4635-4638
Hauptverfasser: Xiong, Yuhao, Chen, Siheng, Ye, Fanggui, Su, Lingjing, Zhang, Cong, Shen, Shufen, Zhao, Shulin
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container_end_page 4638
container_issue 22
container_start_page 4635
container_title Chemical communications (Cambridge, England)
container_volume 51
creator Xiong, Yuhao
Chen, Siheng
Ye, Fanggui
Su, Lingjing
Zhang, Cong
Shen, Shufen
Zhao, Shulin
description We demonstrate a facile and rapid in situ partial oxidation synthetic strategy for the fabrication of a mixed valence state Ce-MOF (MVCM) which exhibits intrinsic oxidase-like activity. Furthermore, on the basis of the excellent catalytic activity of the MCVM, a colorimetric approach for the high-throughput detection of biothiols in serum samples was established.
doi_str_mv 10.1039/c4cc10346g
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Catalysis
Catalytic activity
Cerium - chemistry
Colorimetry
Colorimetry - methods
Humans
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Oxidase
Oxidation
Serums
Strategy
Sulfhydryl Compounds - blood
Synthesis
title Synthesis of a mixed valence state Ce-MOF as an oxidase mimetic for the colorimetric detection of biothiols
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