Synthesis of a mixed valence state Ce-MOF as an oxidase mimetic for the colorimetric detection of biothiols

Synthesis of a mixed valence state Ce-MOF as an oxidase mimetic for the colorimetric detection of biothiols

We demonstrate a facile and rapid in situ partial oxidation synthetic strategy for the fabrication of a mixed valence state Ce-MOF (MVCM) which exhibits intrinsic oxidase-like activity. Furthermore, on the basis of the excellent catalytic activity of the MCVM, a colorimetric approach for the high-th...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (22), p.4635-4638
Hauptverfasser: Xiong, Yuhao, Chen, Siheng, Ye, Fanggui, Su, Lingjing, Zhang, Cong, Shen, Shufen, Zhao, Shulin
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalytic activity
Cerium - chemistry
Colorimetry
Colorimetry - methods
Humans
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Oxidase
Oxidation
Serums
Strategy
Sulfhydryl Compounds - blood
Synthesis
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We demonstrate a facile and rapid in situ partial oxidation synthetic strategy for the fabrication of a mixed valence state Ce-MOF (MVCM) which exhibits intrinsic oxidase-like activity. Furthermore, on the basis of the excellent catalytic activity of the MCVM, a colorimetric approach for the high-throughput detection of biothiols in serum samples was established.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc10346g