Fluorographane (C sub(1)H sub(x)F sub(1-x- delta )) sub(n): synthesis and properties

Fluorographane (C sub(1)H sub(x)F sub(1-x- delta )) sub(n): synthesis and properties

Fluorographane (C sub(1)H sub(x)F sub(1-x- delta )) sub(n) was obtained from graphene by hydrogenation via the Birch reaction with consequent fluorination of the resulting graphane. Fluorographane exhibits fast heterogeneous electron transfer rates and hydrophobicity, which increase with increasing...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (26), p.5633-5636
Hauptverfasser: Sofer, Zdenek, Simek, Petr, Mazanek, Vlastimil, Sembera, Filip, Janousek, Zbynek, Pumera, Martin
Format: Artikel
Sprache:eng
Schlagworte:
Electron transfer
Fluorination
Graphene
Hydrogenation
Hydrophobicity
Synthesis
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Zusammenfassung:Fluorographane (C sub(1)H sub(x)F sub(1-x- delta )) sub(n) was obtained from graphene by hydrogenation via the Birch reaction with consequent fluorination of the resulting graphane. Fluorographane exhibits fast heterogeneous electron transfer rates and hydrophobicity, which increase with increasing fluorination.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc08844a