Template-directed construction of conformational supramolecular isomers for bilayer porous metal-organic frameworks with distinct gas sorption behaviors

A pair of supramolecular isomers of Co(II)-based metal-organic frameworks can be directionally constructed in virtue of solvent templates, which show diverse bilayer networks and lattice packing with the same Co3 SBUs and organic linkers. The two porous materials show distinct gas sorption behaviors...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-04, Vol.51 (27), p.6014-6017
Hauptverfasser:	Chen, Min, Zhao, Hui, Liu, Chun-Sen, Wang, Xi, Shi, Heng-Zhen, Du, Miao
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Benzoates - chemistry Carbon dioxide Carbon Dioxide - chemistry Carbon Dioxide - isolation & purification Cobalt - chemistry Coordination Complexes - chemistry Crystallography, X-Ray Isomerism Isomers Lattices Metal-organic frameworks Models, Molecular Networks Porosity Porous materials Solvents Sorption Surface Properties
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Beschreibung
Zusammenfassung:	A pair of supramolecular isomers of Co(II)-based metal-organic frameworks can be directionally constructed in virtue of solvent templates, which show diverse bilayer networks and lattice packing with the same Co3 SBUs and organic linkers. The two porous materials show distinct gas sorption behaviors at different temperatures, especially their CO2 sorption selectivity.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c5cc00018a