Room-temperature Cu(II)-catalyzed aromatic C-H azidation for the synthesis of ortho-azido anilines with excellent regioselectivity

Room-temperature Cu(II)-catalyzed aromatic C-H azidation for the synthesis of ortho-azido anilines with excellent regioselectivity

Cu(ii)-catalyzed aromatic C-H azidation with azido-benziodoxolone under mild conditions has been described. The primary amine exhibits an excellent ortho-directing effect, providing ortho-azidated anilines as the sole products.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-06, Vol.50 (43), p.5733-5736
Hauptverfasser: Fan, Yunpeng, Wan, Wen, Ma, Guobin, Gao, Wei, Jiang, Haizhen, Zhu, Shizheng, Hao, Jian
Format: Artikel
Sprache:eng
Schlagworte:
Amines
Aniline
Sole
Synthesis
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Zusammenfassung:Cu(ii)-catalyzed aromatic C-H azidation with azido-benziodoxolone under mild conditions has been described. The primary amine exhibits an excellent ortho-directing effect, providing ortho-azidated anilines as the sole products.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc01481b