Gas-phase synthesis and reactivity of Cu super(+)-benzyne complexes
Cu super(+)-benzyne complexes bearing bidentate nitrogen ligands were synthesized in the gas phase for the first time using electrospray ionization mass spectrometry. The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. The structures of products wer...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (79), p.11668-11671 |
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| container_end_page | 11671 |
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| container_issue | 79 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Chai, Yunfeng Shen, Shanshan Weng, Guofeng Pan, Yuanjiang |
| description | Cu super(+)-benzyne complexes bearing bidentate nitrogen ligands were synthesized in the gas phase for the first time using electrospray ionization mass spectrometry. The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. The structures of products were identified by comparing their MS super(n) data with authentic compounds obtained from another generation route. |
| doi_str_mv | 10.1039/c4cc04168b |
| format | Article |
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The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. 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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2014-09, Vol.50 (79), p.11668-11671 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1893885806 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Analyzers Bearing Gas phases Ionization Ligands Mass spectrometry Nitrogen Synthesis |
| title | Gas-phase synthesis and reactivity of Cu super(+)-benzyne complexes |
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