Gas-phase synthesis and reactivity of Cu super(+)-benzyne complexes

Gas-phase synthesis and reactivity of Cu super(+)-benzyne complexes

Cu super(+)-benzyne complexes bearing bidentate nitrogen ligands were synthesized in the gas phase for the first time using electrospray ionization mass spectrometry. The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. The structures of products wer...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (79), p.11668-11671
Hauptverfasser: Chai, Yunfeng, Shen, Shanshan, Weng, Guofeng, Pan, Yuanjiang
Format: Artikel
Sprache:eng
Schlagworte:
Analyzers
Bearing
Gas phases
Ionization
Ligands
Mass spectrometry
Nitrogen
Synthesis
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Cu super(+)-benzyne complexes bearing bidentate nitrogen ligands were synthesized in the gas phase for the first time using electrospray ionization mass spectrometry. The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. The structures of products were identified by comparing their MS super(n) data with authentic compounds obtained from another generation route.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc04168b