Flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/triethylamine

Flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/triethylamine

An efficient and practical catalytic method for the aerobic oxidative transformation of sulfides into sulfoxides, and thiols into disulfides with formic acid/TEA in the presence of a new, readily available, and stable flavin catalyst 5d is described.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (71), p.10295-10298
Hauptverfasser: Murahashi, Shun-Ichi, Zhang, Dazhi, Iida, Hiroki, Miyawaki, Toshio, Uenaka, Masaaki, Murano, Kenji, Meguro, Kanji
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalysts
Disulfides
Ethylamines - chemistry
Ethylamines - metabolism
Flavins - chemistry
Flavins - metabolism
Formates - chemistry
Formates - metabolism
Formic acid
Oxidation-Reduction
Sulfhydryl Compounds - chemistry
Sulfhydryl Compounds - metabolism
Sulfides
Sulfides - chemistry
Sulfides - metabolism
Thiols
Transformations
Triethylamine
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Beschreibung
Zusammenfassung:An efficient and practical catalytic method for the aerobic oxidative transformation of sulfides into sulfoxides, and thiols into disulfides with formic acid/TEA in the presence of a new, readily available, and stable flavin catalyst 5d is described.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05216a