Clathrates of TETROL: selective inclusion of methylcyclohexanones in their energetically unfavorable axial methyl conformations

Clathrates of TETROL: selective inclusion of methylcyclohexanones in their energetically unfavorable axial methyl conformations

3- and 4-Methylcyclohexanone have been isolated exclusively as their energetically disfavoured axial conformers in the host-guest complexes formed upon recrystallization of the novel optically pure host compound, (+)-(2R,3R)-1,1,4,4-tetraphenylbutane-1,2,3,4-tetraol (TETROL), from these cycloalkanon...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-11, Vol.50 (87), p.13353-13355
Hauptverfasser: Barton, B, Caira, M R, Hosten, E C, McCleland, C W, Weitz, S
Format: Artikel
Sprache:eng
Schlagworte:
Clathrates
Inclusions
Methylcyclohexanones
Recrystallization
Supramolecular compounds
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Beschreibung
Zusammenfassung:3- and 4-Methylcyclohexanone have been isolated exclusively as their energetically disfavoured axial conformers in the host-guest complexes formed upon recrystallization of the novel optically pure host compound, (+)-(2R,3R)-1,1,4,4-tetraphenylbutane-1,2,3,4-tetraol (TETROL), from these cycloalkanones.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc06826b