Palladium-catalyzed monoselective C-H borylation of acetanilides under acidic conditions

Palladium-catalyzed monoselective C-H borylation of acetanilides under acidic conditions

A practical Pd-catalyzed reaction was developed to achieve C-H activation/C-B cross-coupling of acetanilides under acidic conditions. The new reaction shows a good functional group tolerance and an exclusive mono-selectivity. This C-H borylation method may provide a generally applicable route for th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (40), p.4854-4856
Hauptverfasser: Xiao, Bin, Li, Yi-Ming, Liu, Zhao-Jing, Yang, Han-Yi, Fu, Yao
Format: Artikel
Sprache:eng
Schlagworte:
Acetanilide
Activation
Bonding
Conversion
Cross coupling
Functional groups
Palladium
Tolerances
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Zusammenfassung:A practical Pd-catalyzed reaction was developed to achieve C-H activation/C-B cross-coupling of acetanilides under acidic conditions. The new reaction shows a good functional group tolerance and an exclusive mono-selectivity. This C-H borylation method may provide a generally applicable route for the conversion of C-H moieties into many other types of bonds.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc31737k