The design and synthesis of an innovative octacarboxy-silsesquioxane building block

The design and synthesis of an innovative octacarboxy-silsesquioxane building block

An octacarboxy-silsesquioxane was designed and synthesised through a multiple-step regioselective reaction. This novel hybrid inorganic-organic compound presents highly attractive features for application as a building block, as it has a robust, rigid structure and a high number of carboxylic coordi...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (75), p.11008-11011
Hauptverfasser: Shanmugan, Swaminathan, Cani, Damiano, Pescarmona, Paolo P
Format: Artikel
Sprache:eng
Schlagworte:
Rigid structures
Robustness
Symmetry
Synthesis
Synthesis (chemistry)
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Beschreibung
Zusammenfassung:An octacarboxy-silsesquioxane was designed and synthesised through a multiple-step regioselective reaction. This novel hybrid inorganic-organic compound presents highly attractive features for application as a building block, as it has a robust, rigid structure and a high number of carboxylic coordination sites organised in a cubic symmetry.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03756a