MeOTf-induced carboannulation of arylnitriles and aromatic alkynes: a new metal-free strategy to construct indenones

MeOTf-induced carboannulation of arylnitriles and aromatic alkynes: a new metal-free strategy to construct indenones

MeOTf-induced carboannulation of arylnitriles and aromatic alkynes for synthesis of indenones under metal-free conditions has been described. When ortho-substituted benzonitriles were used, indeno[1,2-c]isoquinolines were formed.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (21), p.2775-2777
Hauptverfasser: Yan, Xiaoyu, Zou, Song, Zhao, Peng, Xi, Chanjuan
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Alkynes - chemistry
Benzonitrile
Isoquinolines - chemistry
Mesylates - chemistry
Molecular Structure
Nitriles - chemistry
Strategy
Synthesis
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Zusammenfassung:MeOTf-induced carboannulation of arylnitriles and aromatic alkynes for synthesis of indenones under metal-free conditions has been described. When ortho-substituted benzonitriles were used, indeno[1,2-c]isoquinolines were formed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc00088a