Poly(trifluoromethyl)azulenes: structures and acceptor properties

Poly(trifluoromethyl)azulenes: structures and acceptor properties

Six new poly(trifluoromethyl)azulenes prepared in a single high-temperature reaction exhibit strong electron accepting properties in the gas phase and in solution and demonstrate the propensity to form regular π-stacked columns in donor-acceptor crystals when mixed with pyrene as a donor.

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Veröffentlicht in:Chem. Commun 2014-01, Vol.50 (47), p.6263-6266
Hauptverfasser: Clikeman, Tyler T, Bukovsky, Eric V, Kuvychko, Igor V, San, Long K, Deng, Shihu H M, Wang, Xue-Bin, Chen, Yu-Sheng, Strauss, Steven H, Boltalina, Olga V
Format: Artikel
Sprache:eng
Schlagworte:
Columns (structural)
Crystals
Gas phases
Pyrenes
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Beschreibung
Zusammenfassung:Six new poly(trifluoromethyl)azulenes prepared in a single high-temperature reaction exhibit strong electron accepting properties in the gas phase and in solution and demonstrate the propensity to form regular π-stacked columns in donor-acceptor crystals when mixed with pyrene as a donor.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc00510d