Interaction of formaldehyde with a water-tolerant frustrated Lewis pair

Interaction of formaldehyde with a water-tolerant frustrated Lewis pair

A facile complexation of formaldehyde with the water-tolerant frustrated Lewis pair (FLP) B(C F ) /PtBu and its Al-analog under ambient conditions is reported. Unprecedented formaldehyde adducts 1, 2 and 4 have been identified and crystallographically characterized.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-03, Vol.53 (22), p.3205-3208
Hauptverfasser: Ghattas, Ghazi, Bizzarri, Claudia, Hölscher, Markus, Langanke, Jens, Gürtler, Christoph, Leitner, Walter, Subhani, Muhammad Afzal
Format: Artikel
Sprache:eng
Schlagworte:
Adducts
Complexation
Crystallography
Formaldehyde
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Beschreibung
Zusammenfassung:A facile complexation of formaldehyde with the water-tolerant frustrated Lewis pair (FLP) B(C F ) /PtBu and its Al-analog under ambient conditions is reported. Unprecedented formaldehyde adducts 1, 2 and 4 have been identified and crystallographically characterized.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc08044h