Probing the role of an Fe super(IV) tetrazene in catalytic aziridination

Probing the role of an Fe super(IV) tetrazene in catalytic aziridination

An iron(iv) tetrazene complex has been synthesized that is an important addition to a previously proposed catalytic aziridination cycle. It provides two key insights about the aziridination: an iron(iv) imide is formed and this imide can bind an additional ligand in the cisposition.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (90), p.13967-13970
Hauptverfasser: Cramer, SAlan, Hernandez Sanchez, Raul, Brakhage, Desirae F, Jenkins, David M
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalysts
Imides
Ligands
Synthesis (chemistry)
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Zusammenfassung:An iron(iv) tetrazene complex has been synthesized that is an important addition to a previously proposed catalytic aziridination cycle. It provides two key insights about the aziridination: an iron(iv) imide is formed and this imide can bind an additional ligand in the cisposition.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05124f