Beryllium bis(diazaborolyl): old neighbors finally shake hands

Beryllium bis(diazaborolyl): old neighbors finally shake hands

The synthesis of a linear beryllium bis(diazaborolyl) compound featuring the first non-cluster bond between boron and beryllium has been achieved through the reaction of Yamashita's lithium diazaborolide and BeCl2. In accord with the established chemistry of beryllium, the bonding is polar cova...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (4), p.737-740
Hauptverfasser: Arnold, T, Braunschweig, H, Ewing, W C, Kramer, T, Mies, J, Schuster, J K
Format: Artikel
Sprache:eng
Schlagworte:
Beryllium
Beryllium compounds
Boron compounds
Chemical bonds
Covalence
Lithium
Spectroscopic analysis
Synthesis (chemistry)
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Zusammenfassung:The synthesis of a linear beryllium bis(diazaborolyl) compound featuring the first non-cluster bond between boron and beryllium has been achieved through the reaction of Yamashita's lithium diazaborolide and BeCl2. In accord with the established chemistry of beryllium, the bonding is polar covalent in character, as determined by structural and spectroscopic analysis, as well as reactivity studies.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc08519a