Oxygen reduction catalyzed by a water-soluble binuclear copper(ii) complex from a neutral aqueous solution

A water-soluble binuclear Cu complex, synthesized using a polypyridine-polyamide ligand, was able to catalyze oxygen reduction to water from neutral aqueous solutions. Electrocatalytic results suggested that one Cu center was first reduced by one electron to form a Cu Cu species, which reacted with O to give a superoxide radical intermediate.